Thermodynamics |
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Introduction | What is this thing called Thermodynamics??? | Definitions | Thermal Equilibrium and Zeroth Law | Limitations |
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First Law | Work, Heat, Energy, and the First Law | Work, Heat, Energy, and the First Law (simplied) | Derivatives | Derivatives Exercise | Reversibility, Enthalpy, and Heat Capacity |
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Second Law | Things to Think About | Observations and Second Law of Thermodynamics | Alternative Approach - the Clausis Inequality | Consequences of the Second Law | Consequences of the Second Law (simplified) | Carnot Principle - motivation and examples | Equivalence of Second Law Statements* |
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Third Law | Third Law of Thermodynamics | Consequences of Third Law* |
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Development of Thermodynamics | The Thermodynamic Network | Network Exercise | Equations of State (EOS) |
EOS Example, Reading Tables, and Numerical Analysis | EOS Exercises | Thermochemistry |
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We can combine these two observations into the
The Second Law of Thermodynamics:
- With no external input, a system will tend toward disorder
- No system can be developed which completely converts heat to work