Natural Dyes

=Natural Dyes - An Eco-friendly Approach=

Vikas Premzada, Department of Sericulture, Acharya Narendra Dev College, University of Delhi, Govind Puri, Kalkaji, Delhi 110 019.

Natural dyes are dyes derived from animal or plant material without any chemical treatment. They are obtained from sources like flowers, leaves, insects, bark roots etc.; however, they are not readily available and involve an extraction process. In prehistoric times, natural colourants were usually obtained from berries, blossoms, barks and roots. They were applied to the fibre without any pretreatment of the dye-material or the textile. In the middle of the nineteenth century, introduction of synthetic dyes marked the decline in the use of natural dyes. However, there are certain ancient art forms such as Kalmkari, which continue to use the natural dyes. A few examples for historical natural dyes are as follows:


 * Indigo: One of the most important and popular dyes from ancient times till today. It is obtained from the leaves of Indigfera turquoise.


 * Logwood: The tree is fairly large and the freshly cut wood is colourless until it is exposed to air.
 * Madder: The valuable dye pigment that give Turkey Red Colour.



In the present scenario, several advantages conferred by natural dyes make them an attractive option over synthetic dyes. These are as follows:


 * Biodegradable
 * Non-toxic
 * Environment Friendly
 * Aesthetically appealing resulting in employment generation and utilization of wasteland.
 * Easy extraction of colours by boiling the plants, berries, leaves, bark or flower heads in water.

Despite these advantages, use of natural dyes is practiced in certain clusters only. These include art forms like Kalmkari, commercial practices like Ikat weaving, Block Printing, Boutique work etc. This can be attributed to the limitations imposed by these dyes, which are as follows:


 * No assurance of shade repeatability
 * Extraction process laborious and not economical
 * Variability in the quality and quantity of extraction depending upon the age and season of the plant, tree, leaves or fruit and hence standardization is difficult.
 * Most dyes need a mordant to fix the colour

Natural dyestuffs can be divided into two groups;

I) Non-mordant dyes (Substantive) and II) Mordant dyes (Adjective).

The majority of natural dyes need mordant, which act as a dye fixing agent forming a link between dyestuff and fibre. Thus, it helps to produce faster shades by forming an insoluble compound of mordant and dyestuff within the fibre itself. The four most commonly used mordants are as follows:


 * 1) Alum/Potassium sulphate, obtained in the form of white crystals is a popular and safe mordant to use.
 * 2) Chrome/Potassium dichromate, sold in the form of orange crystals is a popular and safe mordant, in fact the most mordant and is widely used. It is sensitive to light.
 * 3) Iron/Ferrous sulphate can be obtained as soft green crystals. It is one of the most important and one of the oldest known mordants known and is still extensively employed.
 * 4) Tin/Stannous chloride sold as off-white crystals, must be used carefully. It is an important mordant for silk and cotton.

Besides these metallic mordants, a number of tannin containing substances (such as myrabolans and sumach), tannic acid and oil mordants are also in use. Among tannins, Myrabolan is a fruit of several kinds of trees such as Terminalia chebula and Myrabolanus chebula. The bulk of tannin i.e. ellagitannic acid is in the peel of the fruit. Sumach consists of the leaves and twigs of several species of Rhus, such as Rhus coriaria, which yields the best sumach. Oil mordants are used mainly in the dyeing of Turkey Red Colour from a natural dye Madder. The main function of the oil-mordant is to form a complex with alum used as the main mordant. Recently, Sulphonated oils or Turkey Red Oils (TRO) have shown to give Turkey Red Colour of superior fastness and hue. TRO are obtained by treating oil with concentrated sulphuric acid.

Different mordant will give different colour with same dye solution. For example, for log wood dye, Alum gives violet and purplish grey, Chrome gives turquoise blue, Iron gives dark grey to black and tin gives Purple colour.

Attractive colours can be obtained by mixing different dyestuff in the same dye bath. After completion of one dye, other can be mixed. Different dyestuff can be boiled separately and mixed in various proportions or they can be boiled together but mordanting is essential during or after dyeing. As the quality of the extract varies with the age, season, and other ecological conditions of the source, it is extremely difficult to standardize the shades.

Natural dyeing is not advisable to dye huge quantities or bulk but small lots can be introduced to get very special effects. Sometimes, natural dyed yarns are dull and muddy. With the right treatment and careful selection of the mordants and dyestuffs, the colours can be made bright but the problem of the standardization of the shade remains.